8Apr2007
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The remarkable advances made in spectroscopy (the branch of science concerned with the investigation and measurement of spectra produced when matter interacts with or emits electromagnetic radiation) during the nineteenth century allowed the spectrum of the sun to he examined for the first time, with results which proved to be of foundational importance. The presence of a hitherto unknown yellow line in that spectrum, without any known terrestrial parallel, led to the discovery of helium. Over the period 1859–60, the frequencies of a series of four lines observed in the solar spectrum were measured with what, for those days, was amazing accuracy – roughly one part in ten thousand (Angstrom 1868). The precision of these measurements of the visible line spectrum of atomic hydrogen led to the development of a new science: "spectral numerology" (Pais 1991, 142). This was an attempt to account for the relationship of the observed spectral lines with some fundamental mathematical equation.
The breakthrough, when it came, was simple and elegant. Working only on the basis of the four frequencies reported by Angstrom, J. J. Balmer found that he could exactly reproduce the frequencies by means of the following formula:
b = 2, a = 3, 4 ... Balmer series (visible)
b = 3, a = 4, 5 ... Paschen series (infrared)
b = 4, a = 5, 6 . . . Brackett series (far infrared)
b = 5, a = 6, 7 . . . Pfund series (far infrared)
b = 6, a = 7, 8 ... Humphreys series (far infrared)
By March 6, 1913, the Danish physicist Niels Bohr realized the significance of what Balmer had uncovered (Pais 1991, 143–55). On the basis of a quantum mechanical interpretation of the hydrogen atom, Bohr was able to derive Balmer's formula in two manners. For the first time, it became clear that Balmer's formula corresponded to aspects of the fundamental structure of the hydrogen atom.
Heisenberg worked keeping close to the experimental evidence about spectra .. . Schrodinger worked from a more mathematical point of view, trying to find a beautiful theory for describing atomic events . . . He was able to extend de Broglie's ideas and to get a very beautiful equation, known as Schrodinger's wave equation, for describing atomic processes. Schrodinger got this equation by pure thought, looking for some beautiful generalization of de Broglie's ideas, and not by keeping close to the experimental development of the subject in the way Heisenberg did.
The differences in approach are highly significant. Heisenberg worked outwards from the experimental evidence; Schrodinger sought an elegant theory which would then account for that evidence. The two, as it proved, converged. The quest for beauty and the quest for truth met at a common point. This point is clearly hinted at in Heisenberg's reflections on his work (Heisenberg 1971, 59, 68):
I had the feeling that, through the surface of atomic phenomena, I was looking at a strangely beautiful interior, and felt almost giddy at the thought that I now had to probe this wealth of mathematical structures nature had so generously spread out before me . . . If nature leads to mathematical forms of great simplicity and beauty – coherent systems of hypotheses, axioms, etc...we cannot help thinking that they are "true," that they reveal genuine features of beauty.
The general drift of this analysis will be clear. A strong doctrine of creation (such as that associated with Christianity) leads to the expectation of a fundamental convergence of truth and beauty in the investigation and explanation of the world, precisely on account of the grounding of that world in the nature of God. The correlation in question is not arbitrary or accidental, but corresponds to the reflection of the nature of the creator in the ordering and regularity of creation.
Alister
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